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Nist standard reference database 46.pdf
This is the Best matching only button.
Remember, it is just as important to know what is absent as it is to know what is present.
In this way of viewing the mass spectrum, the peak at m/z 269 in methyl stearate becomes the M 29 peak (loss of an ethyl radical) and the peak at m/z 267 becomes the M 31 peak (loss of a methoxy radical).
Otherwise, the format of the two databases is similar.This moves the cursor to the To field.Smit, University of Amsterdam; Processor.The inclusion of databases and their order of search can be set from the Libraries or Options tab of the various Search dialog boxes (see Figure 27 and Figure 31 as examples).In these cases, the difference between the Match Factors for different spectra is very small, and the search cannot be assured of providing the correct unique answer.The specific formats and names are covered by the respective copyrights of the individual companies.There are six such panes in the Lib.Stop after entering each letter.It is possible to state whether the spectra currently in the nist MS Search Program s Spec List pane are to be added to or replaced by the automatic import.Retrieves a spectrum with unique nist Mass Spectral Data Center s Archive ID number (in mainlib and replib only).The Program does not use or require the installation of special nist fonts.Chemical Substructure Identification by Mass Spectral Library Searching.
When a search is performed of a user database that contains Tags (Field titles it is possible to constrain that search based on the Tag (Field title) and the partial or whole contents of the Tag (Field title).
There are two panes below this in an area labeled Substructure information: Prob.
Click on the on the right side of the Type field.Five new Constraints have been added: Tags in Comment, meat grinder user manual Peptide Sequences, Peptide Mobile Protons, Peptide Charge, and Peptide Number of Residues.9 Version.0g of the MS Search Program Previous version,.0f, of the MS Search Program Tab Displays Title Bar, Tool Bar, and Status Bar Neutral Loss Display The Lib.The Substructure Information utility is used in the evaluation of a Hit List using the nist/EPA/NIH Mass Spectral Database because each spectrum is indexed according to the substructures that make up the structure 2003 mercedes benz e500 manual of the compound that resulted in the spectrum.The Create File with Spectrum in X option creates a text file that contains the spectrum that is in X of the ChemStation Stack display.If peaks are present at higher m/z values, the abscissa will have a right-pointing arrowhead at its right end.After the desired databases have been indexed (this Figure.Msms tab for data acquired using triple quad.Select Tools from the Main Menu and then select (Re)Index Exact Mass.If a spectrum containing a chemical structure is selected, the RMB menu s command Send to will result in a Send to menu that can have up to three additional structure editor items.Imported spectra integer m/z and no mass defect correction.The black lines indicate the peaks in the mass spectrum that the MS Interpreter can explain.On the right side of the movable vertical divider bar are three separate Windows: Search Spectrum/Spec List Spectrum, top; Compare, middle; and Hit List Spectrum, bottom.Clicking on the spectrum entry will result in displaying the spectrum information.
If one of the abbreviations is not understood, highlight it by using the Mouse and a detailed explanation appears at the bottom of the Substructural information area.
All spectra that are from the nist Replicates Database appear at the top of the list.
The other factor (InLib) is a measure of the probability of the compound actually being in the searched databases.